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Penicillazine, a Unique Quinolone Derivative with 4H-5,6-Dihydro-1,2-oxazine Ring System from the Marine Fungus Penicillium sp. (Strain #386) from the South China Sea

注意：本论文已在Tetrahedron 56 (2000) 9607-9609发表
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Yongcheng Lin,a,* Zhiyu Shao,a Guangce Jiang,a Shining Zhou,a Jiwen Cai,a L. L. P. Vrijmoedb
and E. B. Gareth Jonesb,c
aDepartment of Applied Chemistry, Zhongshan University, Guangzhou 510275, People's Republic of China
bDepartment of Biology and Chemistry, City University of Hong Kong, Hong Kong, People's Republic of China
cBIOTEC, National Center for Genetic Engineering and Biotechnology, National Science and Technology Development Agency,
Bangkok, Thailand

Abstract：Penicillazine (1) is a new compound with both quinolone and 4H-5,6-dihydro-1,2-oxazine ring systems that was isolated from aculture of the marine fungus Penicillium sp. (strain #386). Its structure was elucidated using spectroscopic methods, primarily 2D NMR techniques, and was con?rmed by an X-ray diffraction analysis. Variations in the 1H NMR spectrum of penicillazine (1) were observed over a 658C temperature range.

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